The George W. Bush Presidential Library holds more than 1,200 cubic feet of audiovisual materials (46,000 audio and video tapes, and 375,000 still photographs) and nearly 4 million electronic photographs created by the White House Photo Office.
A great many historic photographs and audio/video materials are in the public domain and available online:
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Fee Schedule for Audiovisual Reproduction
White House Photo Archive Gallery
Tee Ball on the South Lawn Photograph Gallery
September 11, 2001 Photograph Gallery
White House Barney Cams (videos)
Provided as lithographs, these photos were taken during the Administration of President George W. Bush